KU chemists reveal breakthrough that leads to cleaner hydrogen energy.
University of Kansas chemists reveal a breakthrough that could lead to cleaner hydrogen energy.
University of Kansas announced KU chemists and U.S. Department of Energy’s Brookhaven National Laboratory have taken a big step toward splitting hydrogen and oxygen molecules to make pure hydrogen without using fossil fuels.
KU said results from experiments have laid bare the complete reaction mechanisms for an important group of “water-splitting” catalysts. The KU and Brookhaven work means scientists are closer to making pure hydrogen from renewable energy, an energy source that could contribute to a greener future for the nation and world.
Their findings appear this week in Proceedings of the National Academy of Sciences.
Co-Author and Associate Professor of Chemistry James Blakemore, whose research in Lawrence forms the basis of the discovery, shared a comment about the research.
James Blakemore, Co-Author and Associate Professor of Chemistry said:
Understanding how the chemical reactions that make clean fuels like hydrogen work is very challenging — this paper represents the culmination of a project that I started in my very first year at KU.
“Our paper presents data that were hard-won from specialized techniques to understand how a certain catalyst for hydrogen generation does the job,” Blakemore said. “The techniques that were used both here at KU and Brookhaven are quite specialized. Implementing these allowed us to get a full picture of how to make hydrogen from its constituent parts, protons and electrons.”
KU said Blakemore’s research was the foundation of the breakthrough. He took his work to Brookhaven for research using pulse radiolysis, as well as other techniques, at their Accelerator Center for Energy Research. Brookhaven is one of only two places in the nation housing equipment that enables pulse radiolysis experiments.
Brookhaven Chemist Dmitry Polyansky, a co-author of the paper, shared a comment about the research.
Dmitry Polyansky, Brookhaven Chemist said:
It’s very rare that you can get a complete understanding of a full catalytic cycle.
“These reactions go through many steps, some of which are very fast and cannot be easily observed.”
KU said Blakemore and his collaborators made the discovery by studying a catalyst that is based on pentamethylcyclopentadienyl rhodium complex, which is [Cp*Rh] for short. They focused on the Cp* (pronounced C-P-”star”) ligand paired with the rare metal rhodium because of hints from prior work showing that this combination would be suitable for the work.
Blakemore shared a comment about the research.
“Our rhodium system turned out to be a good target for the pulse radiolysis,” Blakemore said. “The Cp* ligands, as they’re called, are familiar to most organometallic chemists, and really chemists of all stripes. They’re used to support many catalysts and can stabilize a variety of species involved in catalytic cycles. One key finding of this paper gives fresh insight into how the Cp* ligand can be intimately involved in the chemistry of hydrogen evolution.”
But Blakemore stressed the findings could lead to other improved chemical processes besides producing clean hydrogen.
“In our work, we hope that chemists will see a study about how a common ligand, Cp*, can enable unusual reactivity,” the Blakemore said.
“This unusual reactivity is relevant to the hydrogen story, but it’s actually bigger than this because Cp* is found in so many different catalysts. Chemists normally think of catalysts as being based on metals. In this way of thinking, if you’re making a new molecule, the metal is the key actor that brings the constituent parts together. Our paper shows that this isn’t always the case. Cp* can be involved in stitching the pieces together to form products.”
Blakemore said he hoped this paper could be an opening that leads to improvements in other catalysts and systems that rely on Cp* ligands. The breakthrough, which was supported by the National Science Foundation and the DOE Office of Science, could apply more broadly to industrial chemistry. Blakemore is now working on applying techniques like those used in this work to the development of new approaches to recycling of nuclear fuels and handling of actinide species.
KU students at the graduate and undergraduate levels also were involved in research that underpinned the breakthrough.
“This project was a very important training vehicle for students,” Blakemore said. “Graduate student Wade Henke, the first author, is now at Argonne National Laboratory as a postdoc. Graduate student Yun Peng is the second author and kicked off the joint work with Brookhaven; both have now finished their Ph.D.s. Undergraduates also contributed to this project over the years, providing new complexes and insights that we used to frame the story that emerged in this paper.”
“All in all, I consider this a successful project and one that was a real team effort over the years,” Blakemore said.
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KU chemists reveal breakthrough that leads to cleaner hydrogen energy, May 16, 2023
